Blog/Combustion analysis: checking the boiler's efficiency
Contractors

July 4, 2026

5 min read

Updated August 6, 2026

Combustion analysis: protocol, CO thresholds and reading the efficiency

Combustion analysis is not an optional flourish at the end of a visit. The French order of 15 September 2009 requires, at the annual service of a boiler from 4 to 400 kW, an assessment of its efficiency and of its air pollutant emissions, and its article 3 splits the reading of ambient carbon monoxide into three bands, one of which means shutting down on the spot. Here is the protocol, the thresholds that stand up, and the basis on which the analyser calculates the efficiency it displays.

Contents

The French order of 15 September 2009 requires, as part of the annual service of boilers from 4 to 400 kW, an assessment of the boiler's efficiency, an assessment of whether it is correctly sized, and an assessment of its air pollutant emissions. Its article 3 sets out how to read the carbon monoxide measured in the ambient air: a normal situation below 10 ppm, a situation deemed abnormal between 10 and 50 ppm, and a serious and immediate danger at 50 ppm and above, with an instruction to keep the boiler shut down. The efficiency the analyser displays is quoted on a net calorific value basis, which the 3CL-DPE 2021 method caps at 111% for natural gas.

What the analysis has to prove, and what the rules expect of it

What the annual service has to cover

The annual service is not a cleaning package. The order of 15 September 2009 sets out its content, and every line below carries your liability if it is skipped.

Required operation What that means on site
Inspection of the boiler and of the heat distribution and control installations, and cleaning and adjustment where necessary Checking the appliance but also the circuit and the controls, not just the heat exchanger
Assessment of the boiler's efficiency Analyser measurement, under stabilised conditions, with an instrument whose make and reference are recorded
Assessment of whether the boiler is correctly sized Comparing the installed output against the real demand, and documenting it
Assessment of the boiler's air pollutant emissions Carbon monoxide measurement, read against article 3
Provision of the necessary advice on correct use of the installation Temperature, ventilation and programming guidance, in writing

The text covers boilers fired by gaseous, liquid and solid fuels, in the 4 to 400 kW band. It was last amended by the order of 21 November 2022. Assessing correct sizing means setting the installed output against the home's real demand, which Argile recalculates room by room to NF EN 12831-1.

When to run an analysis outside the annual service

  • At commissioning, or after replacing the burner or the gas valve block.
  • After any work touching the air supply, the gas, the nozzle or the flue.
  • On a complaint about smells, soot, spillage or repeated safety lockouts.
  • Before and after descaling or power flushing, so you hold a comparable pair of readings.

Carbon monoxide thresholds and the action each one requires

The measurement is taken in the ambient air of the room, with the appliance running at its rated output, after at least three minutes of operation. The three bands below are those of article 3 of the order, and they are not open to negotiation with the occupant.

Ambient CO concentration Classification Action required
Below 10 ppm Normal situation Continue the service
From 10 to under 50 ppm Situation deemed abnormal Investigate the flue draught and the ventilation of the room
50 ppm and above Serious and immediate danger Instruction to the user to keep the boiler shut down

Preparing the measurement: safety, instrument and conditions

Putting the dwelling into its real operating configuration first

Open the air inlets and check the grilles are not obstructed, then confirm the room is not being put under depression by mechanical extract, a cooker hood or a tumble dryer running. A measurement taken with a window open or the extracts switched off describes a situation that never occurs in use. If you suspect a flue fault, make the site safe before measuring, not afterwards.

Checking the measuring chain before touching the burner

Check the calibration date against the manufacturer's interval, zero the instrument in fresh air, then inspect the probes, seals and hoses. Replace blocked filters and empty the condensate trap. The make and reference of the instrument will have to appear on the certificate, so it is worth confirming it is in order before you start rather than discovering a drift as you write up.

Sampling point, stabilised operation and air supply

Take the sampling point on a straight section, after the appliance and before any dilution. Wait for genuinely stable operation, then record O₂, CO, CO₂, flue gas temperature and draught. On a modulating appliance, measure at several steps: a burner can be faultless at full load and produce CO at the bottom of its range, which is precisely where it spends the season.

Recording and adjusting on site

The quantities to record and the order to take them in

Record ambient CO first, before doing anything else: that is the measurement that decides whether you carry on. Then take O₂, CO and CO₂ in the flue gases, the flue gas temperature, the combustion air temperature and the flue draught. Note the excess air and the calculated efficiency the instrument displays, along with the settings in place. Without the measuring conditions, the values cannot be compared from one visit to the next.

Adjusting combustion without leaving the manufacturer's instructions

Set the air first, then the gas or oil rate, following the manufacturer's instructions strictly: they carry the target values, and they are what counts. Work in small increments, let the appliance settle between adjustments, and recheck modulation at several steps. A sound delta T limits short cycling and helps a condensing boiler stay in its efficient band, which also depends on balancing the emitters.

The usual causes behind an out-of-range reading

Fouling of the heat exchanger or burner: clean before adjusting, or you are compensating one fault with another. Air starvation: obstructed grilles, an over-sealed room, an air supply to redo. Flue: insufficient draught, poor sealing, badly made joints. Condensation on an appliance not designed for it: flue gas temperature too low or return too cold, to be addressed by adjustment or a hydraulic change. Diagnosis comes before the screwdriver.

Reading the efficiency: net and gross calorific value, and flue losses

The basis on which the displayed efficiency is calculated

Almost every analyser displays a combustion efficiency quoted on a net calorific value basis, a reference that excludes the heat of condensation of the water vapour in the flue gases. That is why a figure above 100% appears on a condensing appliance without anything being wrong. The 3CL-DPE 2021 method sets the conversion factor to the gross basis at 1.11 for natural gas, 1.09 for LPG and 1.07 for heating oil, which mechanically caps the net-basis efficiency at 111%, 109% and 107%. The full mechanism is set out in our article on the condensing gas boiler.

What the flue losses actually tell you

Combustion efficiency depends first on flue losses, themselves a function of flue gas temperature and excess air. Cooler flue gases and controlled excess air improve the figure. But the aim is not the lowest possible value: on an appliance not designed to condense, going too low makes it condense inside the flue and destroys the flue system. The adjustment targets a band, not a record.

Spotting a drift rather than reading an isolated value

A single measurement says almost nothing. What speaks is the gap between two visits under the same conditions: CO climbing, excess air drifting, flue gas temperature rising for the same service. Archive the readings year on year and compare against the conventional efficiency of the 3CL method matching the appliance's type and age to place the gap.

Recording the job and keeping the file

The analysis report: what it has to carry

A useful report fits on one page and carries the values measured before and after adjustment, the measuring conditions (output, setpoints, operating mode, settling time), the adjustments made and the recommendations. Add the time-stamped printout from the analyser and two photographs. This format ties directly into the service contract and what it has to contain.

The service certificate: deadline, retention, required statements

Article R. 224-41-8 of the code de l'environnement sets fifteen days after the visit to issue the certificate. The customer keeps it for at least two years and makes it available to inspectors. The order of 15 September 2009 requires the make and reference of the measuring instrument used to be stated on it, and requires that instrument to be suited to the measurement and checked so the value it gives can be relied on.

What you commit to when you sign the record

A signed record commits you to the state of the installation on that date and under the conditions described, and no further. Write the reservations explicitly: ventilation to be redone, flue to be checked, appliance out of range at one modulation step. Then propose consumption monitoring to show what the adjustment actually did over the season, rather than announcing a percentage saving that nothing will ever confirm.

Key figures

< 10 ppm

Ambient CO, normal situation

≥ 50 ppm

Serious and immediate danger

15 days

Deadline for the certificate

Frequently asked questions

The threshold that stands up applies to CO measured in the ambient air, not in the flue gases. Article 3 of the French order of 15 September 2009 calls the situation normal below 10 ppm, abnormal between 10 and 50 ppm with mandatory investigation of the flue draught and the ventilation of the room, and a serious and immediate danger at 50 ppm and above, with an instruction to the user to keep the boiler shut down. The reading taken in the flue gases is interpreted against the appliance's own instructions.

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Louis Meneteau

Louis is CPO of Argile. An engineer by training, he spent four years validating calculation software in systems engineering, then three years in software product. He turns the installer's daily reality into product workflows: technical survey, sizing, quotes and subsidy files. His articles describe field gestures rather than principles, because he watches them on site before specifying them.

Further reading

Heat pump sizing note

Calculated to NF EN 12831-1

General information

Beneficiary

Mrs Margaret Hughes

Email

contact@argile.ai

Phone

+44 7700 900457

Works address

7 Rosewood Close, Sheffield

Air-to-water heat pump

Model

Alféa Extensa S. 10

Make

Atlantic

Rated output

10 kW

ηs at 35 °C / 55 °C

195 % / 154 %

COP

3,5

Controller

Classe VI

EPREL no.

2491075

Heat loss of the home

6,0 kW

Output at the design temperature

5,80 kW

3,59 kW

7,78 kW

0 %

60 %

130 %

Coverage of the demand

Equipment output / heat loss of the home

97 %

Sizing of the appliance

Roofs

Transmittance W/m².K

1,8

Area

65,2

Heat loss W/K

135,0

Floors

Transmittance W/m².K

0,6

Area

63,0

Heat loss W/K

15,6

Thermal bridges

Conductivity W/K/m

0,4

Lengths m

33,4

Heat loss W/K

12,5

Façades

Transmittance W/m².K

0,9

Area

162,4

Heat loss W/K

151,4

Openings

Transmittance W/m².K

1,2

Area

5,5

Heat loss W/K

10,9

Air renewal

Air change rate h⁻¹

0,8

Heat loss W/K

102,3

Temperature difference

Outdoor design temperature

-7 °C

Heat pump cut-off temperature

5 °C

Indoor set temperature

19 °C

DeltaT

14,0 °C

Construction coefficient

Volume (area × ceiling height)

378,0 m³

Equivalent G value

1,13 W/m³/K

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